House Remodeling Surrey

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These choices ensure your renovation project aligns with green building standards, contributing to a healthier indoor environment and potentially lowering your energy bills. Learn more about House Remodeling Surrey here Moreover, their commitment to quality is matched by their dedication to providing an efficient service. Learn more about Canyon Property Projects Ltd. here. They also specialize in fitting energy-efficient lighting and smart home systems, which not only contribute to reducing energy use but also add convenience to your life. Moreover, Canyon Property Projects Ltd. is always on the lookout for innovative technologies and practices that push the envelope in green building. Moreover, they're keen on waste reduction during and after construction.
You'll find that their approach is tailored to meet your business's unique needs, ensuring that the end result not only looks good but also enhances your operational efficiency. Moreover, we regularly benchmark our prices against the market to ensure we remain competitive. You might not be aware, but Canyon Property Projects Ltd. has quietly risen as the undisputed leader in home improvement across House Remodeling Surrey, setting standards that few can match. Whether you're dreaming of a sleek, modern design or a warm, traditional feel, they've got the expertise to bring it to life.
Furthermore, they're proactive in addressing potential issues before they become problems. They also offer guidance on maintaining your new plumbing system to extend its lifespan. They don't just aim to meet your expectations; they strive to exceed them, ensuring every detail is accounted for.

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From the initial consultation to the final walkthrough, they're with you every step of the way, offering personalized solutions tailored to your unique needs and preferences.
They'll guide you through the selection of water-efficient fixtures and eco-friendly materials that reduce your environmental footprint without compromising on style or comfort. They recognize that every home improvement project is as unique as the homeowner themselves. From eco-friendly paints that promote healthier indoor air quality to energy-efficient windows that save on heating costs, every choice has an impact. You'll appreciate their commitment to sustainability and efficiency, as they offer eco-friendly options that can help reduce your home's carbon footprint and save on energy bills.

Choosing Canyon Property means investing in a hassle-free experience, where your project is managed efficiently, within budget, and on time. Embarking on your home improvement journey with Canyon Property Projects Ltd starts with a simple consultation to understand your vision and sustainability goals. Canyon Property Projects Ltd. partners with reputable suppliers, ensuring that only the highest quality materials make it into your project.

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From custom kitchen transformations that breathe new life into your culinary space, to luxurious bathroom upgrades that turn routine into retreat, and full-scale renovation solutions that reimagine your living space - they've got it all.

This means your home improvement isn't just a personal upgrade but a smart, local market-aligned investment.

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Moreover, they're flexible and responsive to changes. By choosing them, you're not only opting for a beautiful home makeover but also contributing to a healthier environment.

As the old saying goes, you never get a second chance to make a first impression, and this rings especially true when it comes to your home. It's not just about delivering a project; it's about ensuring you're delighted long after the work is finished. Expanding your living space with Canyon Property Projects Ltd means unlocking the potential of your home through sophisticated extensions tailored to your lifestyle.

Canyon Property Projects Ltd. emphasizes the importance of quality material selection, guiding you through the plethora of options to find what best suits your vision and budget. Choosing Canyon Property Projects Ltd. means you're not just renovating your house; you're creating a home that reflects your personal style and meets your lifestyle needs. Whether you're looking for sleek modern designs or cozy traditional aesthetics, their team has got you covered.

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It's not just about making your space look good for now; they want to ensure it stands the test of time. Whether you're updating a kitchen, transforming a bathroom, or adding an extension, the materials you choose play a pivotal role in the outcome. Beyond these rooms, Canyon Property Projects can revamp your living areas, bedrooms, and even outdoor spaces, ensuring a cohesive and inviting look throughout your home. Water conservation is another key aspect of their sustainable practices. Choosing Canyon Property Projects Ltd means you're partnering with a team that listens to your needs, respects your budget, and delivers high-quality workmanship on time.
Our team's expertise spans across all areas of home improvement, from initial design and planning to the final touches of decoration. We understand that your home is more than just a space; it's where your life unfolds and memories are made. When you choose Canyon Property Projects Ltd. for your home improvement needs in House Remodeling Surrey, you're not just getting a service provider; you're partnering with artisans who take immense pride in their work. Modern materials offer durability and aesthetic appeal, from classic wood finishes to contemporary composite solutions.
They don't stop there; they also offer exterior makeovers, including landscaping and painting, to boost curb appeal. Read more about House Remodeling Surrey here For instance, if family-friendly neighborhoods in House Remodeling Surrey are seeing a spike in demand, focusing on creating versatile, child-friendly living areas could be a smart move. Outdoor kitchen installation Let's take a closer look at what makes them stand out in the crowded field of home improvement. You'll find that their approach isn't just about reducing waste; it's about innovating solutions that benefit both you and the planet.
They stand by the quality of their work, guaranteeing outcomes that exceed your expectations. You're not just getting a personalized touch; you're assured that every detail, from materials to craftsmanship, is of the highest caliber. Imagine stepping into your backyard to find a perfectly crafted outdoor living space, tailored just for you-this is now within your reach.

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They've got a keen eye on what's trending and what sells, ensuring you're not just upgrading your space but also boosting its market value. Hardwood floor refinishing

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They're committed to using high-quality, durable materials that ensure your outdoor space not only looks fantastic but withstands the test of time.

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As you click through the photos, you'll see drab, outdated spaces reborn into modern, functional areas that enhance daily living. You're not just improving your space; you're investing in a home that's both personally satisfying and appealing to the House Remodeling Surrey market. When you decide to work with them, you're not just hiring a company; you're partnering with a dynamic team of craftspeople, designers, and project managers, all dedicated to bringing your vision to life.

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Our team works closely with you to understand your needs and preferences, making sure that every material selected aligns with your vision and budget. Affordable home remodeling Surrey

You're probably seeking a team that listens, understands, and implements your vision with precision-and that's exactly what they bring to the table. We don't just follow the current styles; we aim to set new benchmarks in home design. This level of service, combined with the quality of work, makes it clear why Canyon Property Projects Ltd has such a strong reputation in House Remodeling Surrey. From the initial consultation, they listen carefully to what you want, taking into account your preferences, lifestyle, and budget.

Opting for a bold color or a unique design can add character and charm, enticing potential buyers or simply making your home the envy of the neighborhood. Foundation repair Being proactive about this hidden problem can save you from unexpected headaches and expenses down the line. With Canyon Property Projects Ltd., you're getting more than just a skilled team; you're getting craftsmen dedicated to excellence. You'll have direct access to a dedicated aftercare team, ready to address any post-completion queries.

Considering the potential damage and repair costs associated with a failure, the investment in replacing these pipes is well justified. Understanding the importance of environmental conservation, Canyon Property Projects Ltd. offers a variety of eco-friendly options to make your home renovation sustainable. At Canyon Property Projects Ltd., we understand that completing your home improvement project on time is as important as the quality of workmanship.

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You'll notice the difference immediately.

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You'll appreciate their transparent communication, as they keep you in the loop at every stage of the project. They understand that each renovation project is as unique as the homeowner themselves, which is why they work closely with you to ensure that your specific desires and requirements are met with precision and care. At Canyon Property Projects Ltd., we're proud to say our team is composed of industry experts who bring a wealth of knowledge and experience to the table. That's where Canyon Property Projects Ltd. Custom home remodeling steps in, offering bespoke solutions that reflect your personal style and functional requirements. Whether you're dreaming of a minimalist living room, a rustic kitchen, or a luxurious bathroom, they've got the expertise to turn your vision into reality.

Sustainability also plays a key role in their design philosophy. They're also adept at navigating local regulations, ensuring your project moves smoothly without any compliance hiccups. By choosing them, you're not just updating your property; you're making a statement about the importance of sustainability in our world today. Our team harnesses the latest design trends and technologies, blending them with timeless aesthetics to create spaces that are both functional and beautiful.

Canyon Property Projects Ltd. boasts a team of highly skilled professionals, each expert in their respective fields, ensuring your project's success from start to finish. It sets the stage for potential buyers, influencing their interest and perceptions before they step inside. They're not just about adding a deck or laying down some patio stones; they're reimagining your entire outdoor space to become a seamless part of your lifestyle. Your vision, budget, and timeline are their top priorities, ensuring a personalized approach to every project, big or small.

Moving beyond the visual transformations, let's hear directly from those who've experienced Canyon Property Projects Ltd.'s remarkable home improvements first-hand. They understand that the kitchen isn't just a place to cook; it's the center of family life and entertainment. But what exactly sets them apart in a market flooded with home improvement options? This open line ensures that your feedback is heard and acted upon, making you an integral part of the process.

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Hearing directly from past clients offers invaluable insights into the real impact of Canyon Property Projects Ltd's work on their lives. You're not just renovating; you're reshaping the way we think about building and living sustainably. Drywall installation and repair Home office renovation You're not just getting a contractor; you're partnering with a team that's committed to quality at every turn.

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While some may believe finding a reliable contractor for both minor repairs and major renovations in House Remodeling Surrey is daunting, Canyon Property Projects Ltd. stands out as the exception.

Canyon Property Projects Ltd.'s approach to innovative design concepts transforms your home into a modern masterpiece that perfectly aligns with your lifestyle. From the initial consultation to the final walkthrough, you're in capable hands. Whether it's the type of flooring that carries from inside to outside without a hitch or the strategic placement of windows and doors to optimize natural light and views, they've got it covered.

You don't need to have a clear vision of your project's end result; that's what the experts at Canyon are there for. Their services cater to both residential and commercial clients, ensuring that no matter the size or scope of your project, you're in capable hands. They don't just upgrade; they transform your bathroom into a sanctuary where you can unwind in style.

Canyon Property Projects Ltd. offers a wide range of commercial upgrade solutions, from complete overhauls to specific area improvements. By selecting materials that aren't only durable but also sourced responsibly, they make sure your renovation isn't just beautiful-it's also kind to the planet. Canyon Property Projects Ltd. understands the importance of staying ahead of market trends and can guide you through the process of selecting the most valuable upgrades for your specific situation, ensuring that your investment pays off when it's time to sell.

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That's why they take a personalized approach from the get-go, ensuring your vision is at the forefront of every decision. Basement waterproofing They're not just about getting the job done; they're about getting it done right, ensuring every project stands the test of time. These transformations aren't just for show. They don't just see you as another project; they see you as a partner in the journey to transform your space.
They'll guide you through every step, ensuring your ideas are heard and incorporated into the final plan. In essence, Canyon Property Projects Ltd doesn't just renovate homes; they're building a greener, more sustainable world, one project at a time. Their team listens to your vision and translates it into reality, ensuring that every inch of your kitchen is tailored to your preferences and lifestyle.
They're committed to transparency, providing clear timelines and honest updates, so there are no surprises along the way. With Canyon Property Projects Ltd., you're in capable hands.

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Fortunately, this company has you covered with solutions that aren't only good for the planet but also for your health and wallet in the long run.
What's more, they understand the importance of staying on schedule and within budget. You'll work closely with their team to define your vision, set clear goals, and establish a timeline that suits your schedule. In their commitment to eco-friendliness, Canyon Property Projects Ltd. integrates sustainable building practices into every project, ensuring your home improvement isn't just visually appealing but environmentally responsible too.

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    Polybutylene
    Names
    Other names
    polybutene-1, poly(1-butene), PB-1
    Identifiers
    ChemSpider
    • none
    ECHA InfoCard 100.111.056 Edit this at Wikidata
    Properties
    (C4H8)n
    Density 0.95 g/cm3[1]
    Melting point 135 °C (275 °F; 408 K)[1]
    Related compounds
    Related compounds
    1-butene (monomer)
    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
    ☒N verify (what is checkY☒N ?)

    Polybutylene (polybutene-1, poly(1-butene), PB-1) is a polyolefin or saturated polymer with the chemical formula (CH2CH(Et))n. Not be confused with polybutene, PB-1 is mainly used in piping.[2]

    Production

    [edit]

    Polybutylene is produced by polymerisation of 1-butene using supported Ziegler–Natta catalysts.

    Catalysts

    [edit]

    Isotactic PB-1 is produced commercially using two types of heterogeneous Ziegler–Natta catalysts.[3] The first type of catalyst contains two components, a solid pre-catalyst, the δ-crystalline form of TiCl3, and solution of an organoaluminum cocatalyst, such as Al(C2H5)3. The second type of pre-catalyst is supported. The active ingredient in the catalyst is TiCl4 and the support is microcrystalline MgCl2. These catalysts also contain special modifiers, organic compounds belonging to the classes of esters or ethers. The pre-catalysts are activated by combinations of organoaluminum compounds and other types of organic or organometallic modifiers. Two most important technological advantages of the supported catalysts are high productivity and a high fraction of the crystalline isotactic polymer they produce at 70–80 °C under standard polymerization conditions.[4][5][6]

    Characteristics

    [edit]

    PB-1 is a high molecular weight, linear, isotactic, and semi-crystalline polymer. PB-1 combines typical characteristics of conventional polyolefins with certain properties of technical polymers.

    PB-1, when applied as a pure or reinforced resin, can replace materials like metal, rubber and engineering polymers. It is also used synergistically as a blend element to modify the characteristics of other polyolefins like polypropylene and polyethylene. Because of its specific properties it is mainly used in pressure piping, flexible packaging, water heaters, compounding and hot melt adhesives.

    Heated up to 190 °C and above, PB-1 can easily be compression moulded, injection moulded, blown to hollow parts, extruded, and welded. It does not tend to crack due to stress.[dubiousdiscuss] Because of its crystalline structure and high molecular weight, PB-1 has good resistance to hydrostatic pressure, showing very low creep even at elevated temperatures.[7] It is flexible, resists impact well and has good elastic recovery.[3][8]

    Isotactic polybutylene crystallizes in three different forms. Crystallization from solution yields form-III with the melting point of 106.5 °C. Cooling from the melt results in the form II which has melting point of 124 °C and density of 0.89 g/cm3. At room temperature, it spontaneously converts into the form-I with the melting point of 135 °C and density of 0.95 g/cm3.[1]

    PB-1 generally resists chemicals such as detergents, oils, fats, acids, bases, alcohol, ketones, aliphatic hydrocarbons and hot polar solutions (including water).[3] It shows lower resistance to aromatic and chlorinated hydrocarbons as well as oxidising acids than other polymers such as polysulfone and polyamide 6/6.[7] Additional features include excellent wet abrasion resistance, easy melt flowability (shear thinning), and good dispersion of fillers. It is compatible with polypropylene, ethylene propylene rubbers, and thermoplastic elastomers.

    Some properties:[7]

    Application areas

    [edit]

    Piping systems

    [edit]

    The main use of PB-1 is in flexible pressure piping systems for hot and cold drinking water distribution, pre-insulated district heating networks and surface heating and cooling systems. ISO 15876 defines the performance requirements of PB-1 piping systems.[9] PB-1's most notable characteristics are weldability, temperature resistance, flexibility and high hydrostatic pressure resistance. The material can be classified PB 125 with a minimum required strength (MRS) of 12.5 MPa. Other features include low noise transmission, low linear thermal expansion, no corrosion and calcification.

    PB-1 piping systems are no longer being sold in North America (see "Class action lawsuits and removal from building code approved usage", below). The overall market share in Europe and Asia is rather small but PB-1 piping systems have shown a steady growth in recent years. In certain domestic markets, e.g. Kuwait, the United Kingdom, Korea and Spain, PB-1 piping systems have a strong position.[8]

    Plastic packaging

    [edit]

    Several PB-1 grades are commercially available for various applications and conversion technologies (blown film, cast film, extrusion coating). There are two main fields of application:

    • Peelable easy-to-open packaging where PB-1 is used as blend component predominantly in polyethylene to tailor peel strength and peel quality, mainly in alimentary consumer packaging and medical packaging.
    • Lowering seal initiation temperature (SIT) of high speed packaging polypropylene based films. Blending PB-1 into polypropylene, heat sealing temperatures as low as 65 °C can be achieved, maintaining a broad sealing window and good optical film properties.

    Hot melt adhesives

    [edit]

    PB-1 is compatible with a wide range of tackifier resins. It offers high cohesive and adhesive strength and helps tailoring the "open time" of the adhesive (up to 30 minutes) because of its slow crystallisation kinetics. It improves the thermal stability and the viscosity of the adhesive.[10]

    Compounding and masterbatches

    [edit]

    PB-1 accepts very high filler loadings in excess of 70%. In combination with its low melting point it can be employed in halogen-free flame retardant composites or as masterbatch carrier for thermo-sensitive pigments. PB-1 disperses easily in other polyolefins, and at low concentration, acts as processing aid reducing torque and/or increasing throughput.

    Thermal insulation

    [edit]

    PB-1 can be foamed.[11] The use of PB-1 foam as thermal insulation is of great advantage for district heating pipes, since the number of materials in the sandwich structure is reduced to one, facilitating its recycling.[12]

    Other applications

    [edit]

    Other applications include domestic water heaters, electrical insulation, compression packaging, wire and cable, shoe soles, and polyolefin modification (thermal bonding, enhancing softness and flexibility of rigid compounds, increasing temperature resistance and compression set of soft compounds).

    Environmental longevity

    [edit]

    Plumbing and heating systems made from PB-1 have been used in Europe and Asia for more than 30 years. First reference projects in district heating and floor heating systems in Germany and Austria from the early 1970s are still in operation today.[8]

    One example is the installation of PB-1 pipes in the Vienna Geothermal Project (1974) where aggressive geothermal water is distributed at a service temperature of 54 °C and 10 bar pressure. Other pipe materials in the same installation failed or corroded and had been replaced in the meantime.[8]

    International standards set minimum performance requirements for pipes made from PB-1 used in hot water applications. Standardized extrapolation methods predict lifetimes in excess of 50 years at 70 °C and 10 bar.[8]

    Class action lawsuits and removal from building code approved usage

    [edit]

    Polybutylene plumbing was used in several million homes built in the United States from around 1978 to 1997. Problems with leaks and broken pipes led to a class action lawsuit, Cox v. Shell Oil, that was settled for $1 billion.[13][14] The leaks were associated with degradation of polybutylene exposed to chlorinated water.[15]

    Polybutylene water pipes are no longer accepted by the United States building codes and have been the subject[16] of class action lawsuits in both Canada and the U.S.[17][18] The National Plumbing Code of Canada 1995 listed polybutylene piping as acceptable for use with the exception of recirculation plumbing. The piping was removed from the acceptable for use list in the 2005 issue of the standard.[19]

    In Australia in March 2023, the Department of Mines, Industry Regulation and Safety reported that Australian homes built in 2019-2020 that had used a certain brand of polybutylene piping, had become the subject of an enquiry due to the significance of water leaks reported.[20][21]

    There is evidence to suggest that the presence of chlorine and chloramine compounds in municipal water (often deliberately added to retard bacterial growth) will cause deterioration of the internal chemical structure of polybutylene piping and the associated acetal fittings.[22] The reaction with chlorinated water appears to be greatly accelerated by tensile stress, and is most often observed in material under highest mechanical stress such as at fittings, sharp bends, and kinks. Localized stress whitening of the material generally accompanies and precedes decomposition of the polymer. In extreme cases, this stress-activated chemical "corrosion" can lead to perforation and leakage within a few years, but it also may not fail for decades. Fittings with a soft compression seal can give adequate service life.[further explanation needed]

    Because the chemical reaction of the water with the pipe occurs inside the pipe, it is often difficult to assess the extent of deterioration. The problem can cause both slow leaks and pipe bursting without any previous warning indication. The only long-term solution is to completely replace the polybutylene plumbing throughout the entire building.[23]

    See also

    [edit]

    References

    [edit]
    1. ^ a b c Mark Alger, Mark S. M. Alger (1997). Polymer science dictionary. Springer. p. 398. ISBN 978-0-412-60870-4.
    2. ^ Whiteley, Kenneth S.; Heggs, T. Geoffrey; Koch, Hartmut; Mawer, Ralph L.; Immel, Wolfgang (2000). "Polyolefins". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a21_487. ISBN 978-3527306732.
    3. ^ a b c d Charles A. Harper (2006). Handbook of plastics technologies: the complete guide to properties and performance. McGraw-Hill Professional. p. 17. ISBN 978-0-07-146068-2.
    4. ^ Hwo, Charles C.; Watkins, Larry K. Laminated film with improved tear strength, European Patent Application EP0459742, Publication date 12/04/1991
    5. ^ Boo-Deuk Kim et al. (2008) U.S. patent 7,442,489
    6. ^ Shimizu, Akihiko; Itakura, Keisuke; Otsu, Takayuki; Imoto, Minoru (1969). "Monomer-isomerization polymerization. VI. Isomerizations of butene-2 with TiCl3 or Al(C2H5)3–TiCl3 catalyst". Journal of Polymer Science Part A: Polymer Chemistry. 7 (11): 3119. Bibcode:1969JPoSA...7.3119S. doi:10.1002/pol.1969.150071108.
    7. ^ a b c d Freeman, Andrew; Mantell, Susan C.; Davidson, Jane H. (2005). "Mechanical performance of polysulfone, polybutylene, and polyamide 6/6 in hot chlorinated water". Solar Energy. 79 (6): 624–37. Bibcode:2005SoEn...79..624F. doi:10.1016/j.solener.2005.07.003.
    8. ^ a b c d e Polybutylene Archived November 30, 2006, at the Wayback Machine
    9. ^ ISO 15876-1:2003 iso.org
    10. ^ T.E. Rolando (1998). Solvent-Free Adhesives. iSmithers Rapra. p. 35. ISBN 978-1-85957-133-0.
    11. ^ Doyle, Lucía (2022-03-20). "Extrusion foaming behavior of polybutene-1. Toward single-material multifunctional sandwich structures". Journal of Applied Polymer Science. 139 (12). doi:10.1002/app.51816. ISSN 0021-8995.
    12. ^ Doyle Gutierrez, Lucia (2022-12-02). A Circular Economy Approach to Multifunctional Sandwich Structures: Polymeric Foams for District Heating Pre-Insulated Pipes (Thesis thesis). HafenCity Universität Hamburg. doi:10.34712/142.35.
    13. ^ Hensler, Deborah R.; Pace, Nicholas M.; Dombey-Moore, Bonita; Giddens, Beth; Gross, Jennifer; Moller, Erik K. (2000). "Polybutylene Plumbing Pipes Litigation: Cox v. Shell Oil". In Hensler, Deborah R. (ed.). Class action dilemmas: pursuing public goals for private gain. Santa Monica, CA: RAND Institute for Civil Justice. pp. 375–98. ISBN 978-0-8330-2601-9.
    14. ^ Schneider, Martin (November 21, 1999). "Pipe problem getting fixed". The Baltimore Sun. Archived from the original on 2012-06-04. Retrieved 2010-07-29.
    15. ^ Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Assessing material performance in chlorinated potable water applications" (PDF). Book Institute of Materials. 759: 863–72. ISSN 1366-5510. Archived from the original (PDF) on 2010-06-22. Retrieved 2010-07-30. also published as: Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Chlorine resistance testing of cross-linked polyethylene piping materials". ANTEC 2001 Proceedings. Boca Raton: CRC Press. pp. 2833–9. ISBN 978-1-58716-098-1.
    16. ^ Pipe dream is nightmare for many, Miami Herald - September 12, 1993
    17. ^ "DuPont USA Settlement of the Canadian Class Action Lawsuits". Archived from the original on 2011-07-06. Retrieved 2010-10-01.
    18. ^ Polybutylene Plumbing Pipe Leak Relief
    19. ^ "Polybutylene (Poly-B) Pressure Water Piping" (PDF). municipalaffairs.alberta.ca. Government of Alberta. 2012-01-06. Retrieved 2019-09-09.
    20. ^ "Information for owners of new homes with polybutylene plumbing pipes" (PDF). commerce.wa.gov.au. March 21, 2023. Archived (PDF) from the original on 12 November 2023. Retrieved November 12, 2023.
    21. ^ Batajtis, Damian (27 March 2023). "Comprehensive Guide to polybutylene Piping Issues and Solutions in Australia". Wizard Leak Detection. Archived from the original on 12 November 2023. Retrieved November 12, 2023.
    22. ^ Cause of failure in polybutylene pipe & acetal fittings http://www.polybutylene.com/poly.html
    23. ^ "Polybutylene Piping". PropEx.com. Archived from the original on 2015-08-29. Retrieved 2015-07-17.

    Further reading

    [edit]

    Polybutylene
    Names
    Other names
    polybutene-1, poly(1-butene), PB-1
    Identifiers
    ChemSpider
    • none
    ECHA InfoCard 100.111.056 Edit this at Wikidata
    Properties
    (C4H8)n
    Density 0.95 g/cm3[1]
    Melting point 135 °C (275 °F; 408 K)[1]
    Related compounds
    Related compounds
    1-butene (monomer)
    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
    ☒N verify (what is checkY☒N ?)

    Polybutylene (polybutene-1, poly(1-butene), PB-1) is a polyolefin or saturated polymer with the chemical formula (CH2CH(Et))n. Not be confused with polybutene, PB-1 is mainly used in piping.[2]

    Production

    [edit]

    Polybutylene is produced by polymerisation of 1-butene using supported Ziegler–Natta catalysts.

    Catalysts

    [edit]

    Isotactic PB-1 is produced commercially using two types of heterogeneous Ziegler–Natta catalysts.[3] The first type of catalyst contains two components, a solid pre-catalyst, the δ-crystalline form of TiCl3, and solution of an organoaluminum cocatalyst, such as Al(C2H5)3. The second type of pre-catalyst is supported. The active ingredient in the catalyst is TiCl4 and the support is microcrystalline MgCl2. These catalysts also contain special modifiers, organic compounds belonging to the classes of esters or ethers. The pre-catalysts are activated by combinations of organoaluminum compounds and other types of organic or organometallic modifiers. Two most important technological advantages of the supported catalysts are high productivity and a high fraction of the crystalline isotactic polymer they produce at 70–80 °C under standard polymerization conditions.[4][5][6]

    Characteristics

    [edit]

    PB-1 is a high molecular weight, linear, isotactic, and semi-crystalline polymer. PB-1 combines typical characteristics of conventional polyolefins with certain properties of technical polymers.

    PB-1, when applied as a pure or reinforced resin, can replace materials like metal, rubber and engineering polymers. It is also used synergistically as a blend element to modify the characteristics of other polyolefins like polypropylene and polyethylene. Because of its specific properties it is mainly used in pressure piping, flexible packaging, water heaters, compounding and hot melt adhesives.

    Heated up to 190 °C and above, PB-1 can easily be compression moulded, injection moulded, blown to hollow parts, extruded, and welded. It does not tend to crack due to stress.[dubiousdiscuss] Because of its crystalline structure and high molecular weight, PB-1 has good resistance to hydrostatic pressure, showing very low creep even at elevated temperatures.[7] It is flexible, resists impact well and has good elastic recovery.[3][8]

    Isotactic polybutylene crystallizes in three different forms. Crystallization from solution yields form-III with the melting point of 106.5 °C. Cooling from the melt results in the form II which has melting point of 124 °C and density of 0.89 g/cm3. At room temperature, it spontaneously converts into the form-I with the melting point of 135 °C and density of 0.95 g/cm3.[1]

    PB-1 generally resists chemicals such as detergents, oils, fats, acids, bases, alcohol, ketones, aliphatic hydrocarbons and hot polar solutions (including water).[3] It shows lower resistance to aromatic and chlorinated hydrocarbons as well as oxidising acids than other polymers such as polysulfone and polyamide 6/6.[7] Additional features include excellent wet abrasion resistance, easy melt flowability (shear thinning), and good dispersion of fillers. It is compatible with polypropylene, ethylene propylene rubbers, and thermoplastic elastomers.

    Some properties:[7]

    Application areas

    [edit]

    Piping systems

    [edit]

    The main use of PB-1 is in flexible pressure piping systems for hot and cold drinking water distribution, pre-insulated district heating networks and surface heating and cooling systems. ISO 15876 defines the performance requirements of PB-1 piping systems.[9] PB-1's most notable characteristics are weldability, temperature resistance, flexibility and high hydrostatic pressure resistance. The material can be classified PB 125 with a minimum required strength (MRS) of 12.5 MPa. Other features include low noise transmission, low linear thermal expansion, no corrosion and calcification.

    PB-1 piping systems are no longer being sold in North America (see "Class action lawsuits and removal from building code approved usage", below). The overall market share in Europe and Asia is rather small but PB-1 piping systems have shown a steady growth in recent years. In certain domestic markets, e.g. Kuwait, the United Kingdom, Korea and Spain, PB-1 piping systems have a strong position.[8]

    Plastic packaging

    [edit]

    Several PB-1 grades are commercially available for various applications and conversion technologies (blown film, cast film, extrusion coating). There are two main fields of application:

    • Peelable easy-to-open packaging where PB-1 is used as blend component predominantly in polyethylene to tailor peel strength and peel quality, mainly in alimentary consumer packaging and medical packaging.
    • Lowering seal initiation temperature (SIT) of high speed packaging polypropylene based films. Blending PB-1 into polypropylene, heat sealing temperatures as low as 65 °C can be achieved, maintaining a broad sealing window and good optical film properties.

    Hot melt adhesives

    [edit]

    PB-1 is compatible with a wide range of tackifier resins. It offers high cohesive and adhesive strength and helps tailoring the "open time" of the adhesive (up to 30 minutes) because of its slow crystallisation kinetics. It improves the thermal stability and the viscosity of the adhesive.[10]

    Compounding and masterbatches

    [edit]

    PB-1 accepts very high filler loadings in excess of 70%. In combination with its low melting point it can be employed in halogen-free flame retardant composites or as masterbatch carrier for thermo-sensitive pigments. PB-1 disperses easily in other polyolefins, and at low concentration, acts as processing aid reducing torque and/or increasing throughput.

    Thermal insulation

    [edit]

    PB-1 can be foamed.[11] The use of PB-1 foam as thermal insulation is of great advantage for district heating pipes, since the number of materials in the sandwich structure is reduced to one, facilitating its recycling.[12]

    Other applications

    [edit]

    Other applications include domestic water heaters, electrical insulation, compression packaging, wire and cable, shoe soles, and polyolefin modification (thermal bonding, enhancing softness and flexibility of rigid compounds, increasing temperature resistance and compression set of soft compounds).

    Environmental longevity

    [edit]

    Plumbing and heating systems made from PB-1 have been used in Europe and Asia for more than 30 years. First reference projects in district heating and floor heating systems in Germany and Austria from the early 1970s are still in operation today.[8]

    One example is the installation of PB-1 pipes in the Vienna Geothermal Project (1974) where aggressive geothermal water is distributed at a service temperature of 54 °C and 10 bar pressure. Other pipe materials in the same installation failed or corroded and had been replaced in the meantime.[8]

    International standards set minimum performance requirements for pipes made from PB-1 used in hot water applications. Standardized extrapolation methods predict lifetimes in excess of 50 years at 70 °C and 10 bar.[8]

    Class action lawsuits and removal from building code approved usage

    [edit]

    Polybutylene plumbing was used in several million homes built in the United States from around 1978 to 1997. Problems with leaks and broken pipes led to a class action lawsuit, Cox v. Shell Oil, that was settled for $1 billion.[13][14] The leaks were associated with degradation of polybutylene exposed to chlorinated water.[15]

    Polybutylene water pipes are no longer accepted by the United States building codes and have been the subject[16] of class action lawsuits in both Canada and the U.S.[17][18] The National Plumbing Code of Canada 1995 listed polybutylene piping as acceptable for use with the exception of recirculation plumbing. The piping was removed from the acceptable for use list in the 2005 issue of the standard.[19]

    In Australia in March 2023, the Department of Mines, Industry Regulation and Safety reported that Australian homes built in 2019-2020 that had used a certain brand of polybutylene piping, had become the subject of an enquiry due to the significance of water leaks reported.[20][21]

    There is evidence to suggest that the presence of chlorine and chloramine compounds in municipal water (often deliberately added to retard bacterial growth) will cause deterioration of the internal chemical structure of polybutylene piping and the associated acetal fittings.[22] The reaction with chlorinated water appears to be greatly accelerated by tensile stress, and is most often observed in material under highest mechanical stress such as at fittings, sharp bends, and kinks. Localized stress whitening of the material generally accompanies and precedes decomposition of the polymer. In extreme cases, this stress-activated chemical "corrosion" can lead to perforation and leakage within a few years, but it also may not fail for decades. Fittings with a soft compression seal can give adequate service life.[further explanation needed]

    Because the chemical reaction of the water with the pipe occurs inside the pipe, it is often difficult to assess the extent of deterioration. The problem can cause both slow leaks and pipe bursting without any previous warning indication. The only long-term solution is to completely replace the polybutylene plumbing throughout the entire building.[23]

    See also

    [edit]

    References

    [edit]
    1. ^ a b c Mark Alger, Mark S. M. Alger (1997). Polymer science dictionary. Springer. p. 398. ISBN 978-0-412-60870-4.
    2. ^ Whiteley, Kenneth S.; Heggs, T. Geoffrey; Koch, Hartmut; Mawer, Ralph L.; Immel, Wolfgang (2000). "Polyolefins". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a21_487. ISBN 978-3527306732.
    3. ^ a b c d Charles A. Harper (2006). Handbook of plastics technologies: the complete guide to properties and performance. McGraw-Hill Professional. p. 17. ISBN 978-0-07-146068-2.
    4. ^ Hwo, Charles C.; Watkins, Larry K. Laminated film with improved tear strength, European Patent Application EP0459742, Publication date 12/04/1991
    5. ^ Boo-Deuk Kim et al. (2008) U.S. patent 7,442,489
    6. ^ Shimizu, Akihiko; Itakura, Keisuke; Otsu, Takayuki; Imoto, Minoru (1969). "Monomer-isomerization polymerization. VI. Isomerizations of butene-2 with TiCl3 or Al(C2H5)3–TiCl3 catalyst". Journal of Polymer Science Part A: Polymer Chemistry. 7 (11): 3119. Bibcode:1969JPoSA...7.3119S. doi:10.1002/pol.1969.150071108.
    7. ^ a b c d Freeman, Andrew; Mantell, Susan C.; Davidson, Jane H. (2005). "Mechanical performance of polysulfone, polybutylene, and polyamide 6/6 in hot chlorinated water". Solar Energy. 79 (6): 624–37. Bibcode:2005SoEn...79..624F. doi:10.1016/j.solener.2005.07.003.
    8. ^ a b c d e Polybutylene Archived November 30, 2006, at the Wayback Machine
    9. ^ ISO 15876-1:2003 iso.org
    10. ^ T.E. Rolando (1998). Solvent-Free Adhesives. iSmithers Rapra. p. 35. ISBN 978-1-85957-133-0.
    11. ^ Doyle, Lucía (2022-03-20). "Extrusion foaming behavior of polybutene-1. Toward single-material multifunctional sandwich structures". Journal of Applied Polymer Science. 139 (12). doi:10.1002/app.51816. ISSN 0021-8995.
    12. ^ Doyle Gutierrez, Lucia (2022-12-02). A Circular Economy Approach to Multifunctional Sandwich Structures: Polymeric Foams for District Heating Pre-Insulated Pipes (Thesis thesis). HafenCity Universität Hamburg. doi:10.34712/142.35.
    13. ^ Hensler, Deborah R.; Pace, Nicholas M.; Dombey-Moore, Bonita; Giddens, Beth; Gross, Jennifer; Moller, Erik K. (2000). "Polybutylene Plumbing Pipes Litigation: Cox v. Shell Oil". In Hensler, Deborah R. (ed.). Class action dilemmas: pursuing public goals for private gain. Santa Monica, CA: RAND Institute for Civil Justice. pp. 375–98. ISBN 978-0-8330-2601-9.
    14. ^ Schneider, Martin (November 21, 1999). "Pipe problem getting fixed". The Baltimore Sun. Archived from the original on 2012-06-04. Retrieved 2010-07-29.
    15. ^ Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Assessing material performance in chlorinated potable water applications" (PDF). Book Institute of Materials. 759: 863–72. ISSN 1366-5510. Archived from the original (PDF) on 2010-06-22. Retrieved 2010-07-30. also published as: Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Chlorine resistance testing of cross-linked polyethylene piping materials". ANTEC 2001 Proceedings. Boca Raton: CRC Press. pp. 2833–9. ISBN 978-1-58716-098-1.
    16. ^ Pipe dream is nightmare for many, Miami Herald - September 12, 1993
    17. ^ "DuPont USA Settlement of the Canadian Class Action Lawsuits". Archived from the original on 2011-07-06. Retrieved 2010-10-01.
    18. ^ Polybutylene Plumbing Pipe Leak Relief
    19. ^ "Polybutylene (Poly-B) Pressure Water Piping" (PDF). municipalaffairs.alberta.ca. Government of Alberta. 2012-01-06. Retrieved 2019-09-09.
    20. ^ "Information for owners of new homes with polybutylene plumbing pipes" (PDF). commerce.wa.gov.au. March 21, 2023. Archived (PDF) from the original on 12 November 2023. Retrieved November 12, 2023.
    21. ^ Batajtis, Damian (27 March 2023). "Comprehensive Guide to polybutylene Piping Issues and Solutions in Australia". Wizard Leak Detection. Archived from the original on 12 November 2023. Retrieved November 12, 2023.
    22. ^ Cause of failure in polybutylene pipe & acetal fittings http://www.polybutylene.com/poly.html
    23. ^ "Polybutylene Piping". PropEx.com. Archived from the original on 2015-08-29. Retrieved 2015-07-17.

    Further reading

    [edit]

    A contractor[1][2] (North American English) or builder (British English),[3][4] is responsible for the day-to-day oversight of a construction site, management of vendors and trades, and the communication of information to all involved parties throughout the course of a building project.[5]

    In the United States, a contractor may be a sole proprietor managing a project and performing labor or carpentry work, have a small staff, or may be a very large company managing billion dollar projects. Some builders build new homes, some are remodelers, some are developers.[6]

    Description

    [edit]

    A general contractor is a construction manager employed by a client, usually upon the advice of the project's architect or engineer.[7] General Contractors are mainly responsible for the overall coordination of a project and may also act as building designer and construction foreman (a tradesman in charge of a crew).

    A general contractor must first assess the project-specific documents (referred to as a bid, proposal, or tender documents). In the case of renovations, a site visit is required to get a better understanding of the project. Depending on the project delivery method, the general contractor will submit a fixed price proposal or bid, cost-plus price or an estimate. The general contractor considers the cost of home office overhead, general conditions, materials, and equipment, as well as the cost of labor, to provide the owner with a price for the project.

    Contract documents may include drawings, project manuals (including general, supplementary, or special conditions and specifications), and addendum or modifications issued prior to proposal/bidding and prepared by a design professional, such as an architect.The general contractor may also assume the role of construction manager, responsible for overseeing the project while assuming financial and legal risks.There are several types of risks can occur include cost overruns, delays, and liabilities related to safety or contract breaches.

    Prior to formal appointment, the selected general contractor to whom a client proposes to award a contract is often referred to as a "preferred contractor".[8]

    Responsibilities

    [edit]

    A general contractor is responsible for providing all of the material, labor, equipment (such as heavy equipment and tools) and services necessary for the construction of the project. A general contractor often hires specialized subcontractors to perform all or portions of the construction work. When using subcontractors, the general contractor is responsible for overseeing the quality of all work performed by any and all of the workers and subcontractors.

    It is a best practice for general contractors to prioritize safety on the job site, and they are generally responsible for ensuring that work takes place following safe practices.

    A general contractor's responsibilities may include applying for building permits, advising the person they are hired by, securing the property, providing temporary utilities on site, managing personnel on site, providing site surveying and engineering, disposing or recycling of construction waste, monitoring schedules and cash flows, and maintaining accurate records.[9]

    The general contractor may be responsible for some part of the design, referred to as the "contractor's design portion" (JCT terminology).[10]

    United Kingdom, Commonwealth and Australia usage

    [edit]

    In the United Kingdom, Australia and some British Commonwealth countries, the term 'general contractor' was gradually superseded by builders during the early twentieth century.[citation needed] This was the term used by major professional, trade, and consumer organizations when issuing contracts for construction work, and thus the term 'general contractor' fell out of use except in large organizations where the main contractor is the top manager and a general contractor shares responsibilities with professional contractors.

    General contractors who conduct work for government agencies are often referred to as "builders". This term is also used in contexts where the customer's immediate general contractor is permitted to sub-contract or circumstances are likely to involve sub-contracting to specialist operators e.g. in various public services.

    United States and Asia usage

    [edit]

    In the United States and Asia, the terms general contractor (or simply "contractor"), prime contractor and main contractor are often interchangeable when referring to small local companies that perform residential work. These companies are represented by trade organizations such as the NAHB.[11]

    Prime contractor

    [edit]

    Prime contractor is a term defined in the US law.[12][13] Statutory definitions of prime contract, prime contractor, subcontract, and subcontractor are in 41 U.S.C. § 8701.[14] The prime contractor term was already defined before the 8 March 1946 passage of An Act To eliminate the practice by subcontractors, under cost-plus-a-fixed-fee or cost reimbursable contacts of the United States, of paying fees or kick-backs, or of granting gifts or gratuities to employees of a cost-plus-a-fixed-fee or cost reimbursable prime contractors or of higher tier subcontractors for the purpose of securing the award of subcontracts or orders. (Pub. L.Tooltip Public Law (United States) 79–319, 60 Stat. 37)

    Licensing requirements

    [edit]

    Licensing requirements to work legally on construction projects vary from locale to locale. In the United States, there are no federal licensing requirements to become a general contractor, but most US states require general contractors to obtain a local license to operate. It is the states' responsibility to define these requirements: for example, in the state of California, the requirements are stated as follows:

    With a few exceptions, all businesses or individuals who work on any building, highway, road, parking facility, railroad, excavation, or other structure in California must be licensed by the California Contractors State License Board (CSLB) if the total cost of one or more contracts on the project is $500 or more.

    In every state that requires a license, a surety bond is required as part of the licensing process, with the exception of Louisiana, where bonding requirements may vary in different parishes. Not all states require General Contractor licenses - these include Vermont, New Hampshire and Maine, among others.

    Licensing qualifications

    [edit]

    Some general contractors obtain bachelor's degrees in construction science, building science, surveying, construction safety, or other disciplines.

    General Contractors often learn about different aspects of construction, including masonry, carpentry, framing, and plumbing. Aspiring general contractors communicate with subcontractors and may learn the management skills they need to run their own company.

    Experience in the construction industry as well as references from customers, business partners, or former employers are demanded. Some jurisdictions require candidates to provide proof of financing to own their own general contracting firm.

    General Contractors often run their own business. They hire subcontractors to complete specialized construction work and may manage a team of plumbers, electricians, bricklayers, carpenters, iron workers, technicians, handymans, architects and roofers. General Contractors build their business by networking with potential clients, buying basic construction tools, and ensuring that their subcontractors complete high-quality work. General Contractors do not usually complete much construction work themselves, but they need to be familiar with construction techniques so they can manage workers effectively. Other reasons include access to specialist skills, flexible hiring and firing, and lower costs.

    General contractor example

    [edit]

    A property owner or real estate developer develops a program of their needs and selects a site (often with an architect). The architect assembles a design team of consulting engineers and other experts to design the building and specify the building systems. Today contractors frequently participate on the design team by providing pre-design services such as providing estimations of the budget and scheduling requirements to improve the economy of the project. In other cases, the general contractor is hired at the close of the design phase. The owner, architect, and general contractor work closely together to meet deadlines and budget. The general contractor works with subcontractors to ensure quality standards; subcontractors specialise in areas such as electrical wiring, plumbing, masonry, etc.

    See also

    [edit]

    References

    [edit]
    1. ^ Davies, Nikolas, and Erkki Jokiniemi. Architect's illustrated pocket dictionary. Oxford: Architectural Press, 2011. 289. Print.
    2. ^ "Collins Dictionary".
    3. ^ "Merriam-Webster".
    4. ^ "Builder vs. Construction Manager".
    5. ^ Hendrickson, Chris. & Au, Tung (2000), The Design and Construction Process. Project Management for Construction: Fundamental Concepts for Owners, Engineers, Architects and Builders, chapter 3
    6. ^ "What's the difference between a developer and a builder?". Chicago Tribune. 2005-01-23. Retrieved 2023-07-18.
    7. ^ Shekhar, R. K. (2005), Academic Dictionary of Architecture, Delhi: Isha Books, 69
    8. ^ Law Insider Inc., Preferred Contractor(s definition [sic], accessed 21 March 2023
    9. ^ Allen, Edward, & Iano Joseph (2009). Fundamentals of Building Construction Materials and Methods. 5th ed. Hoboken, N.J.: John Wiley & Sons.
    10. ^ Joint Contracts Tribunal, Intermediate Building Contract with contractor’s design (ICD), current edition 2019, accessed 7 July 2021
    11. ^ "About NAHB". www.nahb.org. Retrieved 2023-07-18.
    12. ^ Nicastro 2023, p. 1.
    13. ^ Carril & Duggan 2020.
    14. ^ Nicastro 2023, p. 1, Note 5.

    Sources

    [edit]

    Frequently Asked Questions

    Yes, you've got financing and payment plan options available for your big renovation project. These flexible arrangements can make managing the cost easier, letting you focus on bringing your dream home to life.

    Canyon Property Projects Ltd. prioritizes your safety by adhering to strict health protocols, including regular sanitization, wearing protective gear, and maintaining social distancing during all construction projects, ensuring both workers and clients are protected.

    Yes, they can help you get the necessary permits and navigate local building regulations before starting your project. They'll ensure everything's in order to make your renovation process as smooth and compliant as possible.